I had the same problem when I tried to remove my exhaust. This will sound a bit scary, but once I removed the support donuts I used the entire exhaust as a lever arm back and forth below the car to break the exhaust loose from the downpipes - worked really well!!! Once you crank the bolts tight for the downpipes, it seems to drive the exhaust into the downpipes and makes it hard to remove. Once you drop the pipes, slide them back and forth below the car, and if you have any luck the pipes will pop loose. May take a few cycles, but it worked well for me... thought I would never get them loose......
Regards -- Roger