Simple.
You ground the wire from the ice pick to the block [ or any good gnd.] and you slip the pick under a boot at the plug or dist cap and that kills that plug.
So... if you see a noticable rpm difference, then that plug is firing and that cyl. has compression.
If no difference , then that one is not ..
Once you find the one not firing, you have to do further testing as it can be a bad plug wire, bad plug, no compression, bad plug resistor, etc.
If a plug wire is suspect, an easy test is to swap with a known good one [ one you have already seen pass the firing test.]
Of course, these are simple , quick test. The proper test procedure
is to start with a compression test so you know where the engine stands before condemning ignition parts.