I don't see where you are getting the 93C and 120C numbers in the discussion about the TTS in the manual. These numbers sound like they refer to a maximum running temperature for a sensor that might be used to cut off the AC compressor when the engine gets really hot.
I believe that the 20*C @ 9.5 means that the switch will remain closed (i.e. providing ground to the relay) for 9.5 seconds when the coolant temp is -20C. I am looking at 07-14, page 10 in the tech manual.
I don't think that the reference in the manual to a coolant temp of 35 is for a cut-off. It's more for engagement. It means that the switch won't close and provide ground at 35 or higher. If you start the car at -20C, the TTS will cut off the CSV after 9.5 seconds of cranking. At that point the coolant temp would still be -20.
And, sorry, don't know if there are any switches that will engage at temps higher than 35. Mercedes tried to resolve this issue with the hot-start relay that fired the CSV for a second or two regardless of engine temp.
Hope I didn't muddy the (cooling) waters.
CT