There are just simple 3mm thickness, round aluminum sealing rings inside those triangular flanges. One for each exhaust manifold to down pipe joint. Best to do both since they both have to come out of their "sockets" at the same time to lower the exhaust pipes. After tightening and crushing the sealing rings, the gap between the steel flanges should look about like it does in your picture and uniform all around. Using new screws and the correct, original type copper coated steel nuts is a good idea. All of these parts are available easily from most sources for imported car parts.
Regards, Tom Colitt
ClassicAutosLA