Maybe the thermo-time switch has packed it in. It provides ground to the relay when cranking for a cold start. You can test it by connecting a test light or meter to the electrical connection on the valve and ground. You should see voltage when you crank a cold engine. If no voltage, test terminal 85 on the relay harness for ground when cranking.
Maybe the valve is plugged. If the valve is getting power, take it off the manifold and re-connect the power and fuel lines. Run a jumper to ground the valve. Put the valve in a plastic bag, crank the starter, and see if it sprays. If it doesn't you need a new or rebuilt valve.
Good luck,
CT