I was going to correct you concerning the 21.7 gallon tank (my 230sl is 17.2) until I looked it up. Holy tank capacity, gas man, that's a lot of petrol! Was there any good reason to install that huge "ballast" in these semi-light cars? Range? Sign of the times?
As far as the problem itself, I think it is more likely the guage or sending unit. The acute bend in the filler neck makes it hard to fill on "automatic shutoff" mode, I always have to fill slowly and hand-modulate the pump. As long as you are doing that you should be able to fill the tank. Now, assume 18 mpg and drive it for about 350 miles, ignore the guage. Did I mention that it would be a good idea to bring a spare gas can (full) with you on this test?
Best,
g
'64 230sl, fully sorted out...ooops, spoke too soon