I think the colour is just a colour, ideally to allow one to differentiate between old and new, etc. What is important is that you make sure you have coolant designed to meet the requirements of aluminium. Many here will say that you should use MBs own brand coolant. BASF Glysantin is also suitable and has a type specifically designed for aluminium heads. I went down that route because it was vastly cheaper. I would have used MB's own brand if price weren't an issue, but a few changes of Glysantin over the years has done no visible harm.
There is plenty of info on this site about changing coolant. Tons of it. Read it. Personally, I wouldn't sweat trying to squeeze every ounce of old coolant out of the system. If you intend to flush it, that's different, but just doing a change will give you a good 90% solution (no pun intended). (There is some good info on the site on how to flush the engine if you've having problems with cooling,etc).
If you haven't done this before, or don't know when the coolant was last changed, I'd strongly recommend not using the radiator drain plug. They can become seized and corroded. Too much pressure will result in you tearing the plug and its thread off the rad. That's an expensive mistake to make (as I learnt years ago). A safer option is to remove the large hose jubilee clip at the bottom of the rad and drain it that way. You can't go wrong in that respect. It's how I do it even after an expensive repair.
If you open the heater core when draining the coolant, you'll get most of the coolant. Ensure it's open when you refill and allow the engine to warm up, open the thermostat and circulate into the core/rest of the engine, etc, then top up as necessary after the car has run for a bit. As I said, I wouldn't worry about every last drop of the old stuff. Expect to get in around 8.5 - 9 litres or so at best. (80-90% of capacity).
I'd shell out for distilled water rather than tap water. Tap water mineral content will vary enormously depending on where you reside.
Finally, pay attention to the info on the site about re-filling to avoid an air lock, which is unlikely but possible.
Have fun!