It would take some serious investigation to come up with a definitive sequence issued from the Chico DMV office in 1969. As John mentioned, any black plates beginning with Z would have been correct for a new 1969 car. Probably Y would be correct as well; my grandmother's 1969 Chevy wagon purchased in San Francisco started with YIA. It would have to be a very early 1969 to have an X, as John's below; I know of two 1968 cars that had plates starting with X. And a 1970 with A sequence blue plates.
Personally, I sought out a pair of nice black Z plates for my 1969 and registered them through the CA DMV DOM plate program. Like an original Becker or waffle pattern firewall pad, it really completes the classic look.