You have to make sure you are using metric O-rings, and hopefully the dealer supplied you with those. If you use the common 1/8" imperial size, it will be too tight.
I used plumbers waterproof silicone grease when installing on my W111 and they work perfectly smooth. Possibly the O-ring came out of its groove and is binding? If there is not any antifreeze in the system, the valves are easy enough to remove and recheck. O-rings should only have .015" squeeze fit and that is not enough to bind.