Remember guys, zinc, or zinc with a phosphate wash (gold zinc) are sacrificial coatings. The moment they hit the atmosphere they begin to degrade. First, the gold color dissipates and this protective passivation disappears, then the underlying zinc eventually oxidizes and sloughs away leaving you with raw cast iron. The raw cast iron isn't in any danger of "rusting away" like sheet metal, so it becomes more of a cosmetic thing. I've never heard anyone say, "Oh, my cast iron brake calipers rotted away!" If that were to ever happen I'd think there wouldn't be much automobile left...
Remember, the standards of zinc or cadmium plating is done with a salt spray test, and the results are measured in hours, not decades...
The caliper rebuilders (of which I pointed to a few previously in the USA) will do pretty much whatever finish you want on the rebuilt calipers. You can get a plating as noted--still sacrificial and not long for this earth--or paint, baked on or rattle can, or powder coat. And of course, if you paint or powder coat you can get it to look like plating if you so choose.