The 220SE has the two plunger pump and the 250SE and up has the six plunger. Totally different beast and are also timed differently. The two plunger pump only has two pistons.
That being said, timing is of little concern with a two plunger pump because of the way it works. It fires three injectors at once and the fuel sits in the manifold until the intake valve opens up. If you look how it is plumbed, one line from the pump goes to a block and is then distributed to three injectors. So two lines each supplying three injectors gives you six cylinders. If it is waaaay off, then maybe you might have an issue.
I might look elsewhere for the starting issue. Cold start valve, throttle linkages, etc. Has it ever run since the pump was installed? I have a picture somewhere of the timing marks for the 220SE pump if you want. And do know that it is installed at TDC which is different from the six plunger pumps.