James,
I can't bring to your question the perspective it deserves but would like to further the inquiry as far as my ponderings have taken it.
A smaller-diameter piston reacting to a given displacement in a closed system must travel further to dissipate that displacement than must a larger-diameter piston. It's a matter of displaced volume, and the larger piston dissipates a given displacement with less travel, just because it is larger. So the smaller gets pushed further. And then, for me, things get more complicated.
In both cases the full extent of piston travel is thwarted by the presence of brake drums or disc rotors, as designed by persons desiring a braking system; piston travel is stopped short by immovable object, forcing a substitution of pressure for travel. Does this mean that your smaller piston will actually be pushing harder on its brake pad than a larger one would be? After all, it is 'driven' to go further than its larger sibling. And since the 'push' energy behind them is pretty consistent, coming from the same master cylinder, it would seem to result in more pounds per square inch expressed at the smaller one just because the avaiilable surface is lesser. So doesn't it then push harder? (It 'wants' to go further than the other one after all, but can't.) This seems contradictory to common sense but is compelling to me when I stop to look closely.
And, to either further muddy or clear the waters, shall we agree for our purposes that the size of the friction pads intervening between the pistons and braking surfaces will be the same in both cases? --- as this has direct bearing on the pounds per square inch bearing on the rotor. (I propose assuming equal pad size, leaving the possibilities for variation as a possible way to tune a modified system for safe and effective function.)
This is an issue with which I never got fully comfortable, but some rudimentary math guided experimental parts substitutions on much lower-powered cars back in the time when we had more daring, less sense and doubtless stronger bones; and in some cases we ended up with better performing (pretty much exclusively drum-type) brake systems. I've pretty much forgotten how to do a lot of that now, but am confident that we have amongst us those who can shine a stronger and more clear light on the issue.
You raise an excellent and interesting --crucial, even, to those with life and limb involved-- question, James; thanks. And yes, please, let us now hear from those with wide experience of Mercedes brakes.
Cheers,
Denny