rwaw,
You noted that the tank was completely filled and then driven only 20 miles. I think the likely cause was expansion of the gasoline. Gas expands as it warms up, so if it was cooler on the day you filled it and warmer on the day it gushed out, that probably explains it. Same thing happened a time or two in my Sprite until I learned not to fill it so full.
Modern cars usually have a built-in expansion space in the tank to prevent this sort of thing, but these old buggers don't. It's best not to fill it absolutely full. I guess the good news is that your tank handled the pressure well!
George Davis
'69 280 SL Euro manual