Are you looking to just have the valve open when you're cranking the starter, or do you want it to open during warm-up?
If just while cranking, you can hard-wire the ground (85) of the CSV relay -run a wire from where the pink wire connects to the thermo-time switch to ground. This will open the CSV the whole time you are cranking the starter. You could also add a push-button switch to this ground to control the valve.
If you want the CSV to open during, then the four-pin relay would work:
30 - hot in run
86 - hot in run
87 - to valve
85 - ground via push-button
BUT I think you would have to add a diode to the standard CSV power wire to avoid energizing the solenoid on the injection pump, which would probably kill the engine.