Um, if you are removing spark plug wires on a running engine at the spark plug end the 30,000 to 50,000 volts generated by the ignition coil is going to try and find a path to ground. The insulation on the plug end is only good enough to insulate up to the firing voltage of the spark plug and a bit more. It is either going through the side of the boot or through the side of the wire whichever path is of lesser resistance.
It is a better practice to remove spark plug wires from a running engine from the distributor end. That way when the gap between the wire and the cap gets too large to allow the spark you will be holding a spark plug wire that is carrying no voltage rather than one with 50,000 volts seeking a ground. I learned this as a teenager when working on a very high energy ignition system. I pulled the spark plug wires at the plug end and when the gap was great enough the energized spark plug wire found a groung by traveling across my insulated pliers, up my arm, down my body and to my manhood that was resting on the fender. Very painfull lesson.