CJHenderson, you have a lot of research ahead of you if you wish to do this yourself. I agree with Pat, and I also send my heads out to an experienced machine shop. I supply the machine shop with all the factory specifications and any special tools they need to use. If you do wish to do it yourself, there are lots of special tools needed for the job. Mercedes published "special tool catalogs" over the years. Many tools are listed in these as well as in the "BBB" shop manuals. The MB part numbers are furnished so special tools can be ordered. Finding step by step instructions will be hard to find since most dealerships did not even do all the machine work when re-conditioning cylinder heads. Use the "Technical Data Booklets" and the BBBs various versions for specifications on wear limits and machining tolerances.
If your head is not flat, you will need to have it machined first. For valve guides, there is a special MB tool (go/no go gauge) to measure inside diameter wear (one tool for intake another tool for exhaust). Another special tool is used to drive the valve guide out of the head. Another special MB tool is used to install the valve guide (one for intake and one for exhaust). Before installing guides the holes and the outside diameters of the guides should be precisely measured. If the valve guide hole in the head is too large then an oversize guide must be selected, then hole in the head must be sized accordingly with another special MB tool (broach). Once the guide is installed in the head the inside diameter of the guide must be sized with a special tool (reamer) so as to fit your new valves. Sometimes the heads are warmed or the new guides are chilled before installing them in the heads. Once the new valve guides are installed, the real work begins! Valve seats must be machined using special pilot tools and valve seat grinding equipment. On rare occasions a valve seat may need to be replaced. You will at least know how to examine these circumstances. These days it makes sense to replace all the valves with new, since the price of new valves is not significant. If you do not replace all the valves with new, then you will need an expensive valve grinding machine to reface the valves. Specifications for valve seat angles and widths are given in the factory documentation along with permissible wear of valve stems and minimum thicknesses of valve edges after machining. Correct width of valve contact at the valve seat must also be achieved. Etc. Etc.
An experienced automobile machinist, besides having the tools, also has the experience to know how to identify problems or issues and will also have the "feel" of the work and know what typical problems to look for.
Review some internet videos and read some general engine rebuilding manuals to get some general knowledge on reconditioning cylinder heads first.