Hi Gordon,
I had similar behavior with my early 280SL. I've found the fuse for the CSV solenoid blown before, so of course check that first. Many DC voltmeters wont respond very quickly to the short voltage pulse from the thermo-time switch, so you might miss the event, especially if its warmer and the pulse is shorter (by design). It wont pulse at all on a warm engine. You might try hooking up a 12V test light to the solenoid (12v test light from any auto parts store should work). Place it so you can see it from the driver's seat when you turn the key. It should flash on for a short time as soon as you start cranking cold.
When I was first bringing up my engine from its 25yr slumber, I actually hooked up a 12V LED to my solenoid semi-permanently so I could always see for sure it gets voltage. On a cold engine I'll see it come on during the initial cranking for about a second, just long enough to notice, although it should stay on longer if colder. When troubleshooting I have also briefly brushed the solenoid input terminal with a 12V hot lead just to hear the audible click and know it was actuating. ***!!!BEWARE!!!*** Be careful doing that with an unfused lead though, and certainly don't do it unless you are absolutely positive there are no fuel leaks anywhere around the CSV or the intake manifold. There will be a spark if you touch that solenoid with a hot lead. That wont end well if you have any fuel vapor around. Have a halon fire extinguisher around if you try this. Good luck!