Thanks everyone for all the advice.
Doug, yes Melbournes cool weather would fix it, Adelaide is already heating up and 40/ 100 degrees days are not far away! 😀
David/ Pawel, yes, my 64 does not have the firewall plug so access is more complex and time consuming, in fact I cannot find anything in the forum to suggest anyone has ever attempted a heater valve repair without access through the firewall plug. I am sure it is possible just requires expertise to extract the core from under the dash. When was the firewall access hole introduced to W113’s?
I will test the heater levers again and see if there is a combination that shuts off the hot air, but so far this has been elusive on hot days. Why did they make the controls so un-intuitive 😂
rwmastel, yes I think Dynamat would also help insulate the cabin from engine heat, although not the hot air that seems to be the heat source as it wafts in, most noticeably during acceleration. I do have standard exhaust shields in place.
thelews/ dirkbalter, I think yours is the best solution, if that is the root cause of the issue, however finding someone willing to repair it may be a challenge in my city. Plus without a firewall plug, access to the heat core valve is more challenging/ time consuming/ expensive.